Pro je c t K ic ko ff Me e ting L AB-SCAL E DE VE L OPME NT - - PowerPoint PPT Presentation

Pro je c t K ic ko ff Me e ting

L AB-SCAL E DE VE L OPME NT OF A HYBRI D CAPT URE SYST E M WIT H ADVANCE D ME MBRANE , SOL VE NT SYST E M AND PROCE SS INT E GRAT I ON DE

• F

E 0026464

10/ 29/ 2015

L I S T e a m

Pr

• fe ssor

Hunaid Nulwala – Pr inc ipal Inve stigator Dr . David L ue bke

• E

xpe rie nc e d Che mist with E xpe rie nc e in I ndustry, Go ve rnme nt, a nd Ac a de mia

• Stro ng b a c kg ro und in Po lyme rs, I
• nic L

iq uids, Ga s Se pa ra tio ns

• F
• unde r o f T

wo T e c hno lo g y Co mpa nie s

• 40+ Pub lic a tio ns a nd 16+ Pa te nts a nd a pplic a tio ns in Ma te ria l

De ve lo pme nt

• Che mic a l E

ng ine e r Spe c ia lizing in Ca rb o n Ca pture

• F
• rme r ORD Ca rb o n Ca pture T

e c hnic a l Co o rdina to r

• Me mb ra ne Sc ie ntist with E

xpe rie nc e De sig ning , Co nstruc ting a nd Ope ra ting Pe rfo rma nc e Syste ms

CCS T e a m PSU T e a m

Dr . Sc ott Che n Pr

• fe ssor

Har r y Allc oc k Dr . John Pan

• F

a the r o f Pho spha zine Po lyme rs (>630 Artic le s in the Are a )

• Re no wne d Che mist with E

xpe rie nc e in I ndustry, Go ve rnme nt a nd Ac a de mia

• E

xpe rie nc e d Che mic a l E ng ine e r

• Stro ng b a c kg ro und in

se pa ra tio n pro c e sse s a nd the rmo dyna mic s

• F
• unde r o f Ca rb o n

Ca pture Sc ie ntific , L L C

• E

xpe rie nc e d Che mic a l E ng ine e r

• Stro ng b a c kg ro und in

se pa ra tio n pro c e sse s

• F
• unde r o f two te c hnic a l

c o mpa nie s

Pro je c t Org a niza tio n

Pro je c t Ob je c tive s

• Simula tio n o f Me mb ra ne a nd So lve nt Sub syste ms
• Synthe sis a nd Cha ra c te riza tio n o f T

a ilo re d Po lypho spha ze ne s

• F

a b ric a tio n o f I nte rfa c ia lly-Co ntro lle d E nve lo pe (I CE ) Me mb ra ne s

• Optimiza tio n o f Po lyme r, Na no -fille r, a nd F

a b ric a tio n Pro c e ss

• De sig n a nd Co nstruc tio n o f Me mb ra ne T

e st Syste ms

• Mo dific a tio n o f Ab so rb e r a nd Strippe r Units o f So lve nt Syste m
• Optimiza tio n o f So lve nt Syste m fo r Ope ra tio n in Hyb rid Syste m
• De mo nstra tio n o f All Sub syste ms with Simula te d F

lue Ga s

• Co mple tio n o f Pre limina ry E

c o no mic Ana lysis

T e c hnic a l Appro a c h

Pre vio us Me mb ra ne Pro c e ss I nno va tio n (MT R)

Pure Me mb ra ne Hyb rid Me mb ra ne

Stra ig htfo rwa rd Pla nt I nte g ra tio n

ESP Air Generator Air Coal LP Turbine Feed water heat exchangers Induced Fan Feed water Pump Condensate Water Makeup Super heated steam Reheated steam Cold Reheat Feed water Water Boiler

Power Plant

FGD IP Turbine HP Turbine

Clean flue gas

Flue gas

Membrane/Absorption Hybrid Process

High Pressure CO2 Air Air +CO2 Flue Gas

T he T ro ub le with Mixe d Ma trix Me mb ra ne s

CO 2 N2

“T rue ” MMM T ra nspo rt

CO 2 N2

Pa rtic le Bypa ss

I nte rfa c ia lly-Co ntro lle d E nve lo pe (I CE ) Me mb ra ne s

I f yo u c a n’ t b e a t ‘ e m, jo in ‘ e m!

CO 2 N2

• Ma ke s use o f e nve lo pme nt e ffe c ts
• Diffusio n phe no me na de te rmine d b y inte ra c tio ns with the pa rtic le a nd

po lyme r surfa c e

• Adva nc e d po lyme rs a llo w a n e xc e lle nt sta rting po int

Me mb ra ne F a b ric a tio n a nd Optimiza tio n

Na no -pa rtic le Se le c tio n Na no -pa rtic le Mo dific a tio n Me mb ra ne F ilm F a b ric a tio n

Pe rfo rma nc e T e sting

I so c ho ric Syste m I so b a ric Syste m

Wha t is g re a t a b o ut po lypho spha ze ne s?

• Co mpa re d to c la ssic a l o rg a nic po lyme rs, the ino rg a nic b a c kb o ne pro vide s

sta b ility to o xida tio n a nd pho to lysis, a nd re sista nc e to ma ny re a g e nts tha t wo uld de c o mpo se pe tro c he mic a l-b a se d po lyme rs. T he b a c kb o ne a lso g ive s rise to po lyme rs with lo w g la ss tra nsitio n te mpe ra ture s.

• T

he ma c ro mo le c ula r sub stitutio n a ppro a c h a llo ws the synthe sis o f hundre ds o f diffe re nt po lyme rs with a wide ra ng e o f pro pe rtie s ma ny o f whic h c a nno t b e g e ne ra te d fro m c o nve ntio na l po lyme rs.

• T

he se spe c ia l pro pe rtie s inc lude c o ntro l o f me mb ra ne c ha ra c te ristic s, suc h a s hig h tra nsmissio n o f g a se s suc h a s CO 2, c o ntro lle d g la ss tra nsitio n a nd me lting te mpe ra ture s, a nd sta b ility to ma ny c he mic a ls.

• Pro pe rty tuning is a c c o mplishe d b y c ha ng ing a ny o f 250 diffe re nt side g ro ups a nd

the ir ra tio s within the po lyme r.

• F

urthe r c ha ng e s a re po ssib le b y surfa c e re a c tio ns, a nd via c o mpo site s suc h a s inte rpe ne tra ting po lyme r ne two rks. Also b lo c k c o po lyme rs a re a c c e ssib le ..

T he Ma c ro mo le c ula r Sub stitutio n Me tho d

Mor e than 250 diffe r e nt side gr

• ups use d e ithe r

alone or in c ombinations to give se ve r al hundr e d diffe r e nt polyme r s made by this me thod at Pe nn State . E ac h Diffe r e nt Side gr

• up ar

r ange me nts give s a polyme r with diffe r e nt pr

• pe r

tie s and pote ntial use s.

Ca rrying Out Re a c tio ns o n a Hig h Mo le c ula r We ig ht Po lyme r Pre se nts So me Uniq ue Cha lle ng e s a nd Oppo rtunitie s

E xa mple s o f Po lypho spha ze ne Me mb ra ne s

[NP(OCH2CF

3)2]n

[NP(OCH2CF

2CF 2CF 2CF 2H)2]n

T a sks fo r Budg e t Pe rio d 1 (2016)

• T

a sk 2: Co mpute r Simula tio n o f Hyb rid Pro c e ss

• 2.1: Simula tio n o f Me mb ra ne Syste m
• 2.2: Simula tio n o f Ab so rptio n/ Air Stripping Syste m
• 2.3: Simula tio n o f He a t Pump Cyc le
• 2.4: Optimiza tio n o f Hyb rid Pro c e ss
• T

a sk 3: Ge ne ra tio n 0 I CE Me mb ra ne De ve lo pme nt

• 3.1: Po lypho spha ze ne Synthe sis a nd Cha ra c te riza tio n
• 3.2: De sig n a nd Co nstruc tio n o f I

so c ho ric Me mb ra ne Syste m

• 3.3: Ge ne ra tio n 0 I

CE Me mb ra ne Pe rfo rma nc e T e sting

• 3.4: Na no -fille r Pa rtic le Se le c tio n
• T

a sk 4: Mo dific a tio n, I nsta lla tio n, a nd T e sting o f Ab so rptio n Co lumn

• 4.1: Mo dific a tio n o f Ab so rptio n Co lumn
• 4.2: I

nsta lla tio n o f Ab so rptio n Co lumn

• 4.3: Pa ra me tric T

e sting o f Ab so rptio n Co lumn

T a sks fo r Budg e t Pe rio d 2 (2017)

• T

a sk 5: Ge ne ra tio n 1 I CE Me mb ra ne De ve lo pme nt

• 5.1: Po lypho spha ze ne Optimiza tio n a nd Cha ra c te riza tio n
• 5.2: F

a b ric a tio n o f Ge ne ra tio n 1 I CE Me mb ra ne

• 5.3: Ge ne ra tio n 1 I

CE Me mb ra ne Pe rfo rma nc e T e sting

• 5.4: De sig n a nd Co nstruc tio n o f Mixe d Ga s Me mb ra ne T

e sting Syste m

• T

a sk 6: Mo dific a tio n, I nsta lla tio n, a nd T e sting o f Air Strippe r

• 6.1: Mo dific a tio n o f Air Strippe r
• 6.2: I

nsta lla tio n o f Air Strippe r

• 6.3: Pa ra me tric T

e sting o f Air Strippe r

T a sks fo r Budg e t Pe rio d 3 (2018)

• T

a sk 7: I CE Me mb ra ne Sc a le -up a nd Simula te d F lue Ga s T e sting

• 7.1: Po lypho spha ze ne Sc a le -up a nd Cha ra c te riza tio n
• 7.2: F

a b ric a tio n o f Optimize d1 I CE Me mb ra ne

• 5.3: Simula te d F

lue Ga s T e sting

• T

a sk 8: I nitia l T e c hnic a l a nd E c o no mic F e a sib ility Study

• 8.1: Syste m Pe rfo rma nc e Mo de ling
• 8.2: E

c o no mic Ana lysis

• 8.3: Se nsitivity Ana lysis

Sc he dule

Budg e t

Budg e t Pe riod 1 10/ 01/ 15- 09/ 30/ 16 Budg e t Pe riod 2 10/ 01/ 16- 09/ 30/ 17 Budg e t Pe riod 3 10/ 01/ 17- 09/ 30/ 18 T

• ta l Proje c t

NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re NE T L Sha re Cost Sha re L IS

$337,781 $84,445 $330,789 $82,697 $268,345 $67,086 $936,914 $234,228

Pe nn Sta te

$160,000 $40,000 $160,000 $40,000 $160,000 $40,000 $480,000 $120,000

CCS

$276,646 $69,162 $166,051 $41,513 $138,418 $34,605 $581,116 $145,280

T

• ta l

$774,427 $193,607 $656,840 $164,210 $566,763 $141,691 $1,998,030 $499,508

Cost Sha re 80% 20% 80% 20% 80% 20% 80% 20%

T e c hnic a l Risks

• Po lypho spha ze ne Pe rfo rma nc e I

nsuffic ie nt

• I

nsuffic ie nt Co ntro l o f I nte rfa c ia l E nve lo pe

• L

a c k o f Re pro duc ib ility o f Me mb ra ne Re sults Be c a use o f Mino r Diffe re nc e s in F a b ric a tio n Pro c e dure

• E

ne rg y Co nsumptio n in He a t Pump Syste m T

• o Hig h
• Ca pita l Co st fo r So lve nt Syste m T
• o Hig h

Re so urc e Risks

• I

na b ility to L

• c a te Qua lifie d Sta ff
• L
• ss o f Se nio r T

e a m Me mb e r

• L

a c k o f Ana lytic a l Re so urc e s

Ma na g e me nt Risks

• Pro b le ms with I

nitia ting Wo rk Pro c e sse s fo r Ne w Co mpa ny

• Co lla b o ra tio n Pro b le ms Amo ng Org a niza tio ns

I P Risks

• I

P Ag re e me nts No t Re a c he d with Sub c o ntra c to rs

• Othe rs Ma ke Use o f Pro c e ss I

nno va tio ns Be c a use o f L a c k o f I P Pro te c tio n

• Pa te nts No t I

ssue d fo r Po lyme rs

• I

CE Me mb ra ne F a b ric a tio n Me tho ds No t Pa te nta b le

Mile sto ne s: BP 1

• Upda te PMP – 10/ 31/ 2015
• K

ic ko ff Me e ting – 12/ 31/ 2015

• Synthe size a nd Cha ra c te rize 10 Po lypho spha ze ne s – 3/ 31/ 2016
• Co nstruc t I

so c ho ric Pe rfo rma nc e Syste m – 3/ 31/ 2016

• Optimize Hyb rid Pro c e ss – 9/ 30/ 2016
• Do wn-se le c t to 3 Po lypho spha ze ne s – 9/ 30/ 2016
• Do wn-se le c t to 3 Na no -fille rs – 9/ 30/ 2016
• Co mple te Pa ra me tric T

e sting o f CO 2 Ab so rptio n Co lumn – 9/ 30/ 2016

Suc c e ss Crite ria : BP 1

• Co mple tio n o f All Wo rk Pro po se d
• Be st Po lypho spha ze ne Ac hie ve s 150 Ba rre rPe rme a b ility a nd 25 CO 2/ N2

Se le c tivity

• 90% Re mo va l Ac hie ve d in Ab so rb e r T

e sting

• 30% De c re a se in Pa ra sitic Po we r De mo nstra te d Co mpa re d to Ca se 12
• Sub missio n o f Co ntinua tio n Applic a tio n

Mile sto ne s: BP 2

• F

a b ric a te 3 Ge n 1 I CE Me mb ra ne s – 3/ 31/ 2017

• Mo dify Air Stripping Co lumn – 3/ 31/ 2017
• Se le c t Up to T

wo Be st Ge n 1 Me mb ra ne s – 9/ 30/ 2017

• Co nstruc t I

so b a ric Pe rfo rma nc e Syste m – 9/ 30/ 2017

• Co mple te Pa ra me tric T

e sting o f Air Stripping Co lumn – 9/ 30/ 2017

Suc c e ss Crite ria : BP 2

• Co mple tio n o f All Wo rk Pro po se d
• Be st Ge n 1 I

CE Me mb ra ne Ac hie ve s 2500 GPU Pe rme a nc e a nd 25 CO 2/ N2 Se le c tivity

• Suc c e ssful T

e st o f Air Stripping Co lumn with Diffe re nc e in Ab so rptio n a nd Stripping T e mpe ra ture s o f No Mo re tha n 50oC

• Sub missio n o f Co ntinua tio n Applic a tio n

Mile sto ne s: BP 3

• Mo de l Pe rfo rma nc e a nd Co nduc t Ma ss a nd E

ne rg y Ba la nc e s fo r Hyb rid Pro c e ss – 3/ 31/ 2018

• Sc a le -up Optima l Po lypho spha ze ne to 1 kg – 6/ 30/ 2018
• Co nduc t Simula te d F

lue Ga s T e sting o f Ge n 1 I CE Me mb ra ne – 9/ 30/ 2018

• Co mple te T

e c hnic a l a nd E c o no mic F e a sib ility Study a nd Se nsitivity Ana lysis – 9/ 30/ 2018

Suc c e ss Crite ria : BP 3

• Co mple tio n o f All Wo rk Pro po se d
• Sc a le -up Po lyme r Synthe sis to 1 kg
• Be st Ge n 1 I

CE Me mb ra ne Ac hie ve s 5000 GPU Pe rme a nc e a nd 30 CO 2/ N2 Se le c tivity

• E

c o no mic Ana lysis Sho ws Sig nific a nt Pro g re ss to wa rd Ac hie ving a 30% Re duc tio n in Co st o f E le c tric ity

• Sub missio n o f Sta te Po int Da ta T

a b le s

• Sub missio n o f F

ina l Re po rt

Ac kno wle dg e me nt

L iq uid I

• n So lutio ns, Ca rb o n Ca pture Sc ie ntific a nd Pe nn Sta te Unive rsity

g ra te fully a c kno wle dg e the suppo rt o f the Unite d Sta te s De pa rtme nt o f E ne rg y’ s Na tio na l E ne rg y T e c hno lo g y L a b o ra to ry unde r a g re e me nt DE

• F

E 0026464, whic h is re spo nsib le fo r funding the wo rk pre se nte d.

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