PVMD Delft University of Technology Learning objectives External - PowerPoint PPT Presentation
External Quantum Efficiency Ren van Swaaij PVMD Delft University of Technology Learning objectives External Quantum Efficiency (EQE) Learning objectives External Quantum Efficiency (EQE) Internal Quantum Efficiency (IQE) Learning
External Quantum Efficiency René van Swaaij PVMD Delft University of Technology
Learning objectives • External Quantum Efficiency (EQE)
Learning objectives • External Quantum Efficiency (EQE) • Internal Quantum Efficiency (IQE)
Learning objectives • External Quantum Efficiency (EQE) • Internal Quantum Efficiency (IQE) • Obtaining J SC from EQE
Learning objectives • External Quantum Efficiency (EQE) • Internal Quantum Efficiency (IQE) • Obtaining J SC from EQE • Typical EQE measurement setup
Definition External Quantum Efficiency: ratio of the collected electron-hole pairs to the number of incident photons
Definition External Quantum Efficiency: ratio of the collected electron-hole pairs to the number of incident photons
Definition External Quantum Efficiency: ratio of the collected electron-hole pairs to the number of incident photons
Definition External Quantum Efficiency: ratio of the collected electron-hole pairs to the number of incident photons
Definition External Quantum Efficiency: ratio of the collected electron-hole pairs to the number of incident photons _ _ _ ++ +
EQE and IQE EQE
EQE and IQE EQE Reflectivity
EQE and IQE IQE EQE Reflectivity
From EQE to Jsc
From EQE to Jsc 0 1 2 3 4 5 6 φ(λ) [10 18 s -1 m -2 nm -1 ]
From EQE to Jsc 6 5 φ(λ) [10 18 s -1 m -2 nm -1 ] 4 3 2 EQE (λ) · φ (λ) 1 0
From EQE to Jsc 6 40 35 5 30 φ(λ) [10 18 s -1 m -2 nm -1 ] %&& [mA cm -2 ] 4 25 3 20 ) $ 15 J SC (∫ 2 10 EQE (λ) · φ (λ) 1 5 0 0
From EQE to Jsc 6 40 35 5 30 φ(λ) [10 18 s -1 m -2 nm -1 ] %&& [mA cm -2 ] 4 25 3 20 ) $ 15 J SC (∫ 2 10 EQE (λ) · φ (λ) 1 5 0 0
EQE testing setup Xenon lamp
EQE testing setup Xenon lamp Chopper wheel
EQE testing setup Xenon lamp Mono- chromator Chopper wheel
EQE testing setup Solar cell Xenon lamp Mono- chromator Chopper wheel
EQE testing setup Solar cell Xenon lamp Mono- chromator Lock-in Amplifier Chopper wheel
EQE testing setup Solar cell Xenon lamp Mono- chromator Lock-in Amplifier Chopper wheel Computer
EQE testing setup Reference diode Xenon lamp Mono- chromator Lock-in Amplifier Chopper wheel Computer
EQE testing setup Reference diode Xenon lamp Mono- chromator Lock-in Amplifier Chopper wheel Computer
Lock-in Amplifier Reference
Lock-in Amplifier Reference Signal
Lock-in Amplifier Reference Signal Lock-in
Lock-in Amplifier Phase Sensitive Detection:
Lock-in Amplifier Phase Sensitive Detection:
Lock-in Amplifier Phase Sensitive Detection:
Lock-in Amplifier Phase Sensitive Detection:
Summary EQE is the ratio between the collected charge carriers per • second and the incident photons per second, per wavelength
Summary EQE is the ratio between the collected charge carriers per • second and the incident photons per second, per wavelength J SC obtained by multiplying the EQE and light spectrum •
Summary EQE is the ratio between the collected charge carriers per • second and the incident photons per second, per wavelength J SC obtained by multiplying the EQE and light spectrum • Lock-in amplifier to detect low amplitude signal from noise •
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